Qubes OS 2.4.1 Crashes at plymouth-quit-wait.service

My disk is /dev/nvme0n1 in this case I checked in lsblk. I did create the entry but is said one already existed but I cant access it.

I didn’t encounter such issue.
You can try to add the EFI boot entry in your BIOS instead of efibootmgr if your BIOS can do it.

How would I do that

It depends on your motherboard BIOS.
Check your motherboard BIOS manual.
Here is an example:
https://techlibrary.hpe.com/docs/iss/proliant-gen10-uefi/s_adding_boot_option.html

I dont think that version of qubes os compatible with this motherboard rather unlikely I can do anything about it within my skill level