Is there a way to assign a keyboard shortcut to move the window-in-focus between monitors?

You can use wmctrl and xdotool to do it, you use window=$(printf '0x0%x' $(xdotool getwindowfocus)) to get the focused window, and then you move it with wmctrl.

Here is some info on how to work with the window
https://forum.qubes-os.org/t/controlling-xfce-windows-with-wmctrl/22299
https://forum.qubes-os.org/t/tiling-xfce-windows-with-shortcut-keys/22840

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