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Here, you have automated pihole installation:

Tool: Simple Set-up of New Qubes and Software

For a long while now we’ve been talking about methods of helping users set up their systems, and install and configure software. New users in particular find this difficult to deal with. Look at the repeated posts in the Forum about how to set up a VPN. Many of the guides that are produced involve users copying shell scripts into dom0 or templates and running them, and it’s obvious that many people still struggle. Wouldn’t it be better if users could just install a package that did all t…

For lokinet, unman asked for feedback and new tools to add. You will get my vote for lokinet

PS: Your issue is most probably linked to DNS. See Linux troubleshooting - Oxen Docs